You will note that in each type of determination the word "estimated" is used to describe the method.
The Concurrence Method: – in this method the time of death is estimated by evaluating events which happen at or near the time of death, or offer information suggesting a time period for the death event. The Rate Method – in this method the time of death is estimated by evaluating the presence/absence of an indicator in a deceased in conjunction with the known behavior of such indicators. There are two general methods by which investigators determine the time of death: Specifically measuring the time of death and preserving evidence after death. 
In the chemistry laboratory, we can use our understanding of kinetics to both measure and manipulate the timeline of death.
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